曹晓雨，男，1979年9月生，九三学社社员，博士，教授，博士生导师。1997年–2001年，在河南师范大学化学与环境科学学院学习，获工学学士学位；2001年–2006年，在武汉大学化学与分子科学学院物理化学专业（电化学方向）硕博连读，获理学博士学位；2006至今，在河南工业大学化学化工学院从事物理化学的教学和电化学能量储存与转换方面的研究工作。现为郑州市高比能化学电源材料重点实验室主任、中国化学会会员、韩国电子材料研究协会会员、河南省化学与材料青年学者联合会理事、多个国际SCI收录期刊长期审稿人。

近年来，主持国家自然科学基金项目、河南省重点科技攻关计划项目、河南省科技开放合作计划项目、河南省高校科技创新团队支持计划项目、河南省高校科技创新人才支持计划项目、郑州市创新型科技领军人才项目及河南省高等学校青年骨干教师资助计划项目；主持了4项河南省科技成果鉴定（均为国内领先水平），其中2项成果获河南省教育厅科技成果壹等奖；在ACS Applied Materials & Interfaces、Chemical Engineering Journal、Electrochimica Acta等国际刊物上发表SCI收录论文70余篇，其中获河南省自然科学优秀学术论文壹等奖5项；编写学术著作2部；获授权国家发明专利4项。荣获了河南省学术技术带头人、河南省教育厅学术技术带头人、郑州市青年科技专家(郑州市青年科技奖)、河南历史大事年编″时代英模″、河南省优秀硕士学位论文指导教师、郑州市科技创新工作先进个人、河南工业大学毕业设计（论文）优秀指导教师、河南工业大学优秀教师、河南工业大学就业创业工作优秀指导教师、河南工业大学毕业生┄″我心目中最优秀的老师″等荣誉称号。

主持的科研项目：

1. NSFC-河南联合基金培育项目，U1704142，基于钒酸银和钒酸铜放电特性Li₄Ti₅O₁₂复合物材料的制备及电化学性能改善研究，2018.01–2020.12，50万元，在研，主持。

2.河南省科技开放合作计划项目，132106000075，磷酸钒锂复合物的设计合成及性能研究，2013.01–2015.12，45万元，已结项，主持。

3.河南省重点科技攻关计划项目，122102210114，脱锂态锂电池正极材料的制备工艺研究，2012.01–2014.12，20万元，已结项，主持。

4.河南省基础与前沿技术研究计划项目，092300410117，心脏起搏器电池电极材料Ag₂V₄O₁₁的循环性能研究，2009.01–2011.12，已完成，主持。

5.河南省高校科技创新团队支持计划，17IRTSTHN003，清洁能源高效转化，

2017.01–2019.12，100万元，在研，负责人。

6.河南省高校科技创新人才支持计划，2011HASTIT017，锂离子电池新型复

合物电极材料的设计、合成及电化学性能研究，2011.01–2013.12，40万元，已结项，主持。

7.郑州市创新型科技领军人才项目，131PLJRC652，动力型复合锂离子电池电极材料研究，2013.01–2015.12，50万元，已完成，主持。

8.河南省高等学校青年骨干教师计划项目，2009GGJS-059，表面包覆LiV₃O₈作高比能锂二次电池正极材料的电化学循环性能改善研究，2009.01–2011.12，4万元，已完成，主持。

9.郑州市科技攻关计划项目，083SGYG25121-3，锂离子电池关键材料的研究与开发，2008.01–2010.12，4万元，已完成，主持。

10.河南工业大学″省属高校基本科研业务费专项资金″项目，2014YWQN03，

离子掺杂Li₃V₂(PO₄)₃正极材料的合成及电化学性能研究，2014.01–2016.12，5万元，已结项，主持。

11.河南工业大学″省属高校基本科研业务费专项资金″项目，2018RCJH01，高性能可逆锂存储负极材料的合成及电化学性能研究，2018.01–2020.12，8万元，在研，主持。

发表的部分学术论文：

1. Limin Zhu, Wenxuan Li, Lei Wang, Lingling Xie, Qi Yang,Xiaoyu Cao*,Rod-like NaV₃O₈as cathode materials with high capacity and stability for sodium storage, Chemical Engineering Journal, 2019, 372, 1056–1065.

2. Lei Wang, Zehua Wang, Lingling Xie, Limin Zhu*, Xiaoyu Cao*, ZIF-67 derived N-doped Co/C nanocubes as high-performance anode materials for mithium-ion batteries,ACS Applied Materials & Interfaces, 2019, 11 (18), 16619–16628.

3.Limin Zhu, Zehua Wang, Lei Wang, Lingling Xie, Jingjing Li,Xiaoyu Cao*,ZnSe embedded in N-doped carbon nanocubes as anode materials for high-performance Li-ion batteries, Chemical Engineering Journal,2019, 364, 503–513.

4. Limin Zhu, Lingling Xie,Xiaoyu Cao*,LiV₃O₈/polydiphenylamine composites with significantly improved electrochemical behavior as cathode materials for rechargeable lithium batteries, ACS Applied Materials & Interfaces, 2018, 10 (13), 10909–10917.

5. Limin Zhu, Guochun Ding, Jingbou Liu, Ziqi Yu, Lingling Xie*, Xiaoyu Cao*, Graphene-wrapped poly(2,5-dihydroxy-1,4 benzoquinone-3,6-methylene) nanoflowers as low-cost and high-performance cathode materials for sodium-ion batteries,International Journal of Energy Research, 2019,DOI: 10.1002/er.4764.

6.Limin Zhu, Lingling Xie*, Chenguang Bao, Xiangyang Yan, Xiaoyu Cao*,LiNi_1/3Co_1/3Mn_1/3O₂/polypyrrole composites as cathode materials for high-performance lithium-ion batteries,International Journal of Energy Research, accepted.

7.Tianjing Wu, Chenyang Zhang, Guoqiang Zou, Jiugang Hu, Limin Zhu, Xiaoyu Cao*, Hongshuai Hou, Xiaobo Ji*,The bond evolution mechanism of covalent sulfurized carbon during electrochemical sodium storage process,Science China-Materials, 2019, 62 (8), 1127–1138.

8. Jingjing Li, Hongliang Wei, Peng Yu, Lifang Geng, Limin Zhu, Xiaoyu Cao*, Chunsen Liu*, Huan Pang*, A multifunctional self-healing G-PyB/KCl hydrogel: Smart conductive, rapid room-temperature phase-selective gelation, and ultrasensitive detection of alpha-fetoprotein, Chemical Communications, 2019, 55 (55), 7922–7925.

9. Xiaoyu Cao*, Jingbo Liu, Limin Zhu*, Lingling Xie, Polymer electrode naterials for high-performance lithium/sodium-ion batteries: A review, Energy Technology, 2019, 7(7), 1800759.

10. Xiaoyu Cao*, Qiancheng Sun, Limin Zhu*, Lingling Xie, Na₃V₂(PO₄)₃nanoparticles confined in functional carbon framework towards high-rate and ultralong-life sodium storage, Journal of Alloys and Compounds, 2019, 791,296–306.

11. Xinli Yang, Chengguang Bao, Linglingxie, Limin Zhu*, Xiaoyu Cao*, Preparation of LiNi_1/3Co_1/3Mn_1/3O₂/polytriphenylamine cathode composites with enhanced electrochemical performances towards reversible lithium storage, Ceramics International, 2019, 45 (8), 9726–9735.

12. Tianjing Wu, Mingjun Jing, Ye Tian, Li Yang, Jiugang Hu, Xiaoyu Cao, Guoqiang Zou, Hongshuai Hou, and Xiaobo Ji*, Surface-driven energy storage behavior of dual-heteroatoms functionalized carbon material, Advanced Functional Materials, 2019, 29 (17), 1900941.

13. Wanwan Hong, Peng Ge, Yunling Jiang, Li Yang, Ye Tian, Guoqiang Zou, Xiaoyu Cao, Hongshuai Hou*, Xiaobo Ji, Yolk-shell-structured bismuth@N-doped carbon anode for lithium-ion battery with high volumetric capacity,ACS Applied Materials & Interfaces, 2019, 11 (11), 10829–10840.

14. Tianjing Wu, Mingjun Jing, Li Yang, Guoqiang Zou, Hongshuai Hou, Yang Zhang, Yu Zhang, Xiaoyu Cao, Xiaobo Ji* Controllable chain-length for covalent sulfur-carbon materials enabling stable and high-capacity sodium storage, Advanced Energy Materials,2019, 9 (9), 1803478.

15.Limin Zhu, Jingbo Liu, Ziqi Liu, Lingling Xie, Xiaoyu Cao*,Anthraquinones with ionizable sodium sulfonate groups as renewable cathode materials for sodium-ion batteries, ChemElectroChem, 2019, 6 (3), 787–792.

16. Peng Ge, Sijie Li, Laiqiang Xu, Kangyu Zou, Xu Gao, Xiaoyu Cao, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji*Hierarchical hollow-microsphere metal-selenide@carboncomposites with rational surface engineering for advancedsodium storage,Advanced Energy Materials, 2019, 9 (1), 1803035.

17. Lingling Xie, Peng Ge, Limin Zhu, Xiaoyu Cao*, Stabilization of LiV₃O₈rod-like structure by protective Mg₃(PO₄)₂layer for advanced lithium storage cathodes, Energy Technology, 2018, 6 (12), 2479–2487.

18. Peng Ge, Hongshuai Hou, Xiaoyu Cao, Sijie Li, Ganggang Zhao, Tianxiao Guo, Chao Wang, Xiaobo Ji*, Multidimensional evolution of carbon structures underpinned by temperature-induced intermediate of chloride for sodium-ion batteries, Advance Science,2018, 5 (6), 1800080.

19. Xiaoyu Cao*,Qi Yang, Limin Zhu*,Lingling Xie,NaV₃O₈with superior rate capability and cycle stability as cathode materials forsodium ion batteries,Ionics, 2018, 24(3), 943–949.

20.Ganggang Zhao, Guoqiang Zou, Hongshuai Hou*, Peng Ge,Xiaoyu Cao,Xiaobo Ji,Sulfur-doped carbon employing biomass-activated carbon as a carrier with enhanced sodium storage behavior,Journal of Materials Chemistry A, 2017, 5 (46), 24353–24360.

21.Guoqiang Zou, Hongshuai Hou*,Xiaoyu Cao,Peng Ge,Ganggang Zhao, Dulin Yin, Xiaobo Ji,3D hollow porous carbon microspheres derived from Mn-MOFs and their electrochemical behavior for sodium storage, Journal of Materials Chemistry A, 2017, 5 (45), 23550–23558.

22. Limin Zhu,Wenjuan Li, Ziheng Yu, Lingling Xie,Xiaoyu Cao*,Synthesis and electrochemical performances of LiV₃O₈/poly(3, 4-ethylenedioxythiophene) composites as cathode materials for rechargeable lithium batteries, Solid State Ionics, 2017, 310, 30–37.

23. Limin Zhu,Wenjuan Li, Lingling Xie,Xiaoyu Cao*, LiV₃O₈/poly(1,5-diaminoanthraquinone) composite as a high performance cathode material for rechargeable lithium batteries, Materials Letters, 2017, 206, 225–228.

24. Peng Ge,Xiaoyu Cao,Hongshuai Hou,Sijie Li,and Xiaobo Ji*, Rodlike Sb₂Se₃wrapped with carbon: The exploring of electrochemical properties in sodium-ion batteries, ACS Applied Materials & Interfaces, 2017, 9 (40), 34979−34989.

25.Zehua Wang, Xiaoyu Cao*, Peng Ge, Limin Zhu, Lingling Xie, Hongshuai Hou*, Xiaoqing Qiu, Xiaobo Ji,Hollow-sphere ZnSe wrapped around carbon particles as a cycle-stable and high-rate anode material for reversible Li-ion batteries, New Journal of Chemistry, 2017, 41 (14): 6693–6699.

26. Wenjuan Li, Limin Zhu*, Ziheng Yu, Lingling Xie, Xiaoyu Cao*, LiV₃O₈/polytriphenylamine composites with enhanced electrochemical performances as cathode materials for rechargeable lithium batteries, Materials, 2017, 10 (4): 344.

27. Xiaoyu Cao*, Lulu Mo, Limin Zhu*, Lingling Xie, Preparation and electrochemical properties of Li₃V₂(PO₄)_3-xBr_x/carbon composites as cathode materials for lithium-ion batteries, Nanomaterials, 2017, 7(3): 52.

28. Xiaoyu Cao*, Jiejie Zhang, Limin Zhu, Preparation of LiV₃O₈/polypyrrole and their derived LiV₃O₈/carbon composites as cathode materials for lithium rechargeable batteries, Journal of Nanoscience and Nanotechnology, 2015, 15 (9), 7081–7086.

29. Xiaoyu Cao*, Limin Zhu, Hailian Wu, Preparation and electrochemical performances of rod-like LiV₃O₈/carbon composites using polyaniline as carbon source, Electronic Materials Letters,2015, 11 (4), 650–657.

30. Limin Zhu, Xiaoyu Cao*,p-Dopable poly(4-cyano)triphenylamine: A high voltage organic cathode for lithium ion batteries, Materials Letters, 2015, 150, 16–19.

31. Weixin Song, Xiaoyu Cao, Zhenping Wu, Jun Chen, Yirong Zhu, Hongshuai Hou, Qing Lan, X.B. Ji*, Investigation of the sodium ion pathway and cathode behavior in Na₃V₂(PO₄)₂F₃combined via a first principles calculation, Langmuir, 2014, 30 (41), 12438–12446.

32. Weixin Song, Xiaoyu Cao, Zhengping Wu, Jun Chen, Kaili Huangfu, Xiaowen Wang, Yaliang Huang, Xiaobo Ji*, A study into the extracted ion number for NASICON structured Na₃V₂(PO₄)₃in sodium-ion batteries, Physical Chemistry Chemical Physics, 2014, 16 (33), 17681–17687.

33. Xiaoyu Cao*, Shuangqiang Chen, Guoxiu Wang*, Porous carbon particles derived from natural peanut shells as lithium ion battery anode and its electrochemical properties, Electronic Materials Letters, 2014, 10 (4), 819–826.

34. Xiaoyu Cao*, Jiejie Zhang, Rheological phase synthesis and characterization of Li₃V₂(PO₄)₃/C composites as cathode materials for lithium ion batteries, Electrochimica Acta, 2014, 129, 305–311.

35. Hongshuai Hou, Xiaoyu Cao, Yingchang. Yang, Laibing Fang, Chengchi Pan, Xuming Yang, Weixin Song, Xiaobo Ji*, NiSb alloy hollow nanospheres as anode materials for rechargeable lithium ion batteries, Chemical Communications, 2014, 50 (60), 8201–8203.

36. Lingling Xie, Yuandong Xu, Jiejie Zhang, Chengpeng Zhang, Xiaoyu Cao*, Lingbo Qu*, Rheological phase synthesis of Er-doped LiV₃O₈as electroactive material for a cathode of secondary lithium storage, Electronic Materials Letters, 2013, 9 (4), 549–553.

37. Lingling Xie, Xiaoyu Cao*, Lixu Zhang, Zhongxu Dai*, Lingbo Qu, Synthesis and electrochemical properties of LiV₃O₈/PAn composite as a cathode material for lithium secondary batteries, Electronic Materials Letters, 2013, 9 (2), 183–186.

38. Lingling Xie, Liqin You, Xiaoyu Cao*, Chaofeng Zhang, Dawei Song, Lingbo Qu, Co₃(PO₄)₂-coated LiV₃O₈as positive materials for rechargeable lithium batteries, Electronic Materials Letters, 2012, 8 (4), 411–415.

39. Xiaoyu Cao*, Lingling Xie, Ruijuan Wang, A soft chemistry synthetic method for preparing LiNi_0.8Co_0.2O₂with enhanced electrochemical performances, Journal of Solid State Electrochemistry, 2011, 15 (3), 473–478.

40. Xiaoyu Cao*, Chao Yuan, Lingling Xie, Hui Zhan, Yunhong Zhou, Low-temperature synthesis of Cu-doped Li_1.2V₃O₈as cathode for reversible lithium storage, Ionics, 2010, 16 (1), 39–44.

41. Xiaoyu Cao, Lingling Xie, Hui Zhan*, Yunhong Zhou, Large-scale synthesis of Li_1.2V₃O₈as a cathode material for lithium secondary battery via a soft chemistry route, Materials Research Bulletin, 2009, 44 (2): 472–477.

所获学术成果奖励：

1.河南省教育厅科技成果壹等奖，磷酸钒锂复合物的设计合成及性能研究,豫教[2017]3771号，2017年，第一完成人。

2.河南省教育厅科技成果壹等奖，LiV₃O₈/PAn复合物正极材料的制备及电化学性能，豫教[2016]01397号，2016年，第一完成人。

3.河南省第三届自然科学学术奖┄自然科学优秀学术论文壹等奖，Hydrogen peroxide biosensor based on hemoglobin immobilized at graphene, flower-like zinc oxide, and gold nanoparticles nanocomposite modified glassy carbon electrode，河南省人力资源和社会保障厅、河南省科学技术协会，2015年，第三完成人。

4.河南省第三届自然科学学术奖┄自然科学优秀学术论文贰等奖，Rheological phase synthesis and characterization of Li₃V₂(PO₄)₃/C composites as cathode materials for lithium ion batteries，河南省人力资源和社会保障厅、河南省科学技术协会，2015年，第一完成人。

5.河南省第二届自然科学学术奖┄自然科学优秀学术论文壹等奖，Preparation of ZnO-coated LiV₃O₈as cathode materials for rechargeable lithium batteries，河南省人力资源和社会保障厅、河南省科学技术协会，2013年，第一完成人。

6.河南省第二届自然科学学术奖┄自然科学优秀学术论文贰等奖，Synthesis and characterization of lithium trivanadates as cathode materials for rechargeable lithium battery via a new wet chemical synthesis method，河南省人力资源和社会保障厅、河南省科学技术协会，2013年，第一完成人。

7.河南省第二届自然科学学术奖┄自然科学优秀学术论文贰等奖，A soft chemistry synthetic method for preparing LiNi_0.8Co_0.2O₂with enhanced electrochemical performances，河南省人力资源和社会保障厅、河南省科学技术协会，2013年，第一完成人。

8.河南省第二届自然科学学术奖┄自然科学优秀学术论文壹等奖，Co₃(PO₄)₂-coated LiV₃O₈as positive materials for rechargeable lithium batteries，河南省人力资源和社会保障厅、河南省科学技术协会，2013年，第三完成人。

9.河南省首届自然科学学术奖┄自然科学优秀学术论文壹等奖，Low-temperature synthesis of Cu-doped Li_1.2V₃O₈as cathode for reversible lithium storage，河南省人力资源和社会保障厅、河南省科学技术协会，2011年，第一完成人。

10.河南省首届自然科学学术奖┄自然科学优秀学术论文壹等奖，Rheological phase synthesis and characterization of micro-sized Li₄Ti₅O₁₂，河南省人力资源和社会保障厅、河南省科学技术协会，2011年，第二完成人。

11.河南省首届自然科学学术奖┄自然科学优秀学术论文贰等奖，Large-scale synthesis of Li_1.2V₃O₈as a cathode material for lithium secondary battery via a soft chemistry route，河南省人力资源和社会保障厅、河南省科学技术协会，2011年，第一完成人；

12.河南省首届自然科学学术奖┄自然科学优秀学术论文贰等奖，A Novel approach to massive preparation of LiV₃O₈as a cathode material for lithium rechargeable battery，河南省人力资源和社会保障厅、河南省科学技术协会，2011年，第一完成人；

13.河南省第十届自然科学优秀学术论文贰等奖，Facile preparation of Ag₂V₄O₁₁nanoparticles via low-temperature molten salt synthesis method，河南省人力资源和社会保障厅、河南省科学技术厅、河南省科学技术协会，2010年，第一完成人。

联系方式：E-mail:caoxy@haut.edu.cn

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